Product ID:V214,SULFURIC ACID-D2
MSDS Date:01/11/2000
FSC:6810
NIIN:00-551-5231
Status Code:A
MSDS Number: CJZYT

Emergency Phone: 504-908-1222

Info Phone: 504-908-1222

Cage: 1EAB6

Telephone: 504-908-1222

Cage: 1EAB6

DEUTERATED SULFURIC ACID

CAS: 13813-19-9

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

LD50 LC50 Mixture:ORAL LD50 (RAT): 2140 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES/SKIN: LIQUID MAY CAUSE
SEVERE BURNS TO EYES AND SKIN. INHALATION: VAPORS MAY CAUSE SEVERE
IRRITATION OF THE RESPIRATORY SYSTEM. INGESTION: INGESTION IS
HARMFUL AND MAY BE FATAL. MAY CAUSE SEVERE BURNS TO MOUTH, THROAT,
AND STOMACH. MAY HAVE ADVERSE EFFECT ON KIDNEY FUNCTION AND MAY BE
FATAL. CHRONIC: OVER EXPOSURE MAY RESULT IN LUNG DAMAGE. TARGET
ORGANS: RESPIRATORY SYSTEM, EYES, SKIN , TEETH.
Effects of Overexposure:INHALATION OF VAPORS MAY CAUSE SEVERE
IRRITATION OF THE RESPIRATORY SYSTEM, LUNG DAMAGE. LIQUID MAY CAUSE
SEVERE BURNS TO SKIN AND EYES. INGESTION IS HARMFUL AND MAY BE
FATAL. INGESTION MAY CAUSE NAUS EA AND VOMITING. INGESTION MAY
CAUSE SEVERE BURNS TO MOUTH, THROAT, AND STOMACH. MAY HAVE ADVERSE
EFFECTS OF KIDNEY FUNCTION AND MAY BE FATAL.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.

First Aid:CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF
CONSCIOUS, GIVE WATER, MILK OR MILK OF MAGNESIA. IF INHALED, REMOVE
TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT,
IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING BEFORE REUSE.

Flash Point Method:CC
Extinguishing Media:USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE
WATER.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. DO NOT GET WATER
INSIDE CONTAINERS.
Unusual Fire/Explosion Hazard:A VIOLENT EXOTHERMIC REACTION OCCURS WITH
WATER. SUFFICIENT HEAT MAY BE PRODUCED TO IGNITE COMBUSTIBLE
MATERIALS. TOXIC SULFUR DIOXIDE PRODUCED.

Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK.
DO NOT USE WATER. NEUTRALIZE SPILLS AND/OR WASHINGS WITH SODA ASH
OR LIME. WITH CLEAN SHO VEL, PLACE MATERIAL INTO CLEAN, DRY
CONTAINER AND COVER. MOVE CONTAINERS FROM SPILL AREA.
Neutralizing Agent:SODA ASH OR LIME.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN CORROSION-PROOF AREA. KEEP CONTAINERS OUT OF SUN AND AWAY FROM
HEAT.

Respiratory Protection:NONE REQUIRED WHERE APPROPRIATE VENTILATION
CONDITIONS EXIST. IF TLV IS EXCEEDED, A SELF CONTAINED BREATHING
APPARATUS IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
REQUIREMENTS.
Protective Gloves:RUBBER GLOVES.
Eye Protection:SAFETY GOGGLES AND FACE SHIELD.
Other Protective Equipment:UNIFORM, PROTECTIVE SUIT RECOMMENDED.
Work Hygienic Practices:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO
NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE
CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
LABORATORY PROTECTIVE EQUIPMENT: GOGGLES & SHIELDS; LAB COAT & APRON;
VENT HOOD; PROPER GLOVES. PRECAUTIONARY LABEL STATEMENTS: POISON
DANGER. CAUSES SEVERE BURNS, MAY BE FATAL IF SWALLOWED. HARMFUL I F
INHALED. REACTS VIOLENTLY WITH WATER.

HCC:C1
Vapor Pres:0
Spec Gravity:1.86
Solubility in Water:APPRECIABLE,100%.(WATER)
Appearance and Odor:CLEAR, COLORLESS TO LIGHT YELLOW, OILY ODORLESS
LIQUID.

Stability Indicator/Materials to Avoid:YES
WATER, MOST COMMON METALS, ORGANIC MATERIALS, STRONG REDUCING AGENTS,
COMBUSTIBLE MATERIALS, STRONG BASES.
Stability Condition to Avoid:MOISTURE, HEAT.
Hazardous Decomposition Products:OXIDES OF SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS
WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE).

Toxicological Information:TOXICITY TEST RESULTS AND HEALTH EFFECTS ARE
BASED ON THE NON-DEUTERATED PRODUCT. THRESHOLD LIMIT VALUE
(TLV/TWA): 1 MG/M3. PERMISSIBLE EXPOSURE LIMIT (PEL): 1 MG/M3. LD50
(ORAL, RAT)= 2140 MG/KG. CAR CINOGENICITY: NTP: N0, IARC: NO, Z
LIST: NO, OSHA REG: NO.

Transport Information:DOMESTIC (D.O.T.): PROPER SHIPPING NAME: SULFURIC
ACID. HAZARD CLASS: CORROSIVE MATERIAL (LIQUID). UN/NA: UN1830.
LABELS: CORROSIVE. INTERNATIONAL (I.MO.): PROPER SHIPPING NAME:
SULPHURIC ACID. HAZARD CLASS: 8. UN/NA: UN1830. LABELS: CORROSIVE.

Federal Regulatory Information:EPA HAZARDOUS WASTE NUMBER: D002, D003
(CORROSIVE, REACTIVE WASTE)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.